Organometallic Compounds
Organometallic Compounds
Technical Information
Nichia supplies high-purity Titanium, Zirconium, Nickel compounds, etc. produced by Nichia's proprietary techniques. These compounds have many applications such as catalysts for polymerization and organic synthesis and raw materials for high performance electronic materials.
(Metal/Metal Oxide, etc.)
Organometallic Compound, Metal Carboxylate, Metal-Organic Framework
Nichia offers a wide range of organic metal complex compounds. Nichia can synthesize organometallic compounds with ligands of cyclopentadiene and its derivatives, alkoxides, phosphines, and organic acid.
M:Metal element R:Alkyl group or hydrogen
Metallocene Compounds
Titanocene Dichloride
| Substance | Titanocene Dichloride |
|---|---|
| Formula | (C5H5)2TiCl2 |
| CAS No. | 1271-19-8 |
| Applications | Catalysts (Polymerization/Hydrogenation/Organic Synthesis), Raw Materials for Electronics Materials, Curing Agent |
Titanocene Dichloride Technical DataZirconocene Dichloride
| Substance | Zirconocene Dichloride |
|---|---|
| Formula | (C5H5)2ZrCl2 |
| CAS No. | 1291-32-3 |
| Applications | Catalysts (Polymerization/Organic Synthesis), Electronics Materials Stabilizer |
Application of Organic Syntheses to Zirconocene Dichloride
The Negishi reagent (Cp2ZrBu2), derived from zirconocene dichloride, has been used for high-stereoselective and regioselective coupling reactions or cyclization. For example, polysubstituted pentacene derivatives having high carrier mobility were synthesized by using a Negishi reagent.
Synthesis of Polysubstituted Acenes
| Substance | Zirconocene Chloride Hydride（Schwartz Reagent） |
|---|---|
| Formula | (C5H5)2ZrHCl |
| CAS No. | 32342-97-5 |
| Applications | Organic Synthesis |
Nickel Complex
| Substance | Bis(1,5-cyclooctadiene)Nickel(0) |
|---|---|
| Formula | (C8H12)2Ni |
| CAS No. | 1295-35-8 |
| Applications | Catalyst / Organic Synthesis |
Nickel Phosphine Complex
| Substance | Dichlorobis (Triphenylphosphine) Nickel(Ⅱ) |
|---|---|
| Formula | [(C6H5)3P]2NiCl2 |
| CAS No. | 14264-16-5 |
| Application | Catalyst for cross-coupling of Grignard reagents |
![1,3-Bis(diphenylphosphino)ethane] nickel(Ⅱ) Dichloride](../../img/product/catalysts/formula12.png)
| Substance | 1,3-Bis(Diphenylphosphino)ethane] Nickel(Ⅱ) Dichloride |
|---|---|
| Formula | {[(C6H5)2P]2(CH2)3}NiCl2 |
| CAS No. | 15629-92-2 |
| Application | Catalyst for cross-coupling of Grignard reagents (By using an uncommon ligand, it can also be used for asymmetric Grignard coupling reactions.) |
![1,2-Bis(diphenylphosphino)ethane] nickel(Ⅱ) Dichloride](../../img/product/catalysts/formula13.png)
| Substance | 1,2-Bis(Diphenylphosphino)ethane] Nickel(Ⅱ) Dichloride |
|---|---|
| Formula | {[(C6H5)2P]2(CH2)2}NiCl2 |
| CAS No. | 14647-23-5 |
| Applications | Catalyst for cross-coupling of Grignard reagents (By using an uncommon ligand, it can also be used for asymmetric Grignard coupling reactions.) |
Synthesis of prototypes is available upon request.
Metal Carboxylate
Metal Oxide Thin Film
GO (Gallium Oxide)
20µm、Ra：0.26nm
ITO (Indium Tin Oxide)
PZT (Titanium Zirconium Lead Oxide)
STO（SrTiO3）
| Y(CF3COO)3 | Yttrium Trifluoroacetate |
|---|---|
| Ba(CF3COO)2 | Barium Trifluoroacetate |
| Cu(CF3COO)2 | Copper Trifluoroacetate |
| (Applications) Superconducting Thin Films | |
Y(CF3COO)3
Ba(CF3COO)2
Cu(CF3COO)2Raw Materials for Metal Oxide Thin Films
*The substances in bold letters in the figure are the substances that can be offered. Contact a Nichia representative to inquire about a prototype synthesis.
MOF/PCP
What is MOF/PCP (Metal-Organic Framework/Porous Coordination Polymer)?
MOF/PCP is a new porous material consisting of a regular combination of metal ions and organic compound ligands. In addition to having a vast specific surface area and regular micropores that exceed those of activated carbon and zeolite, MOF/PCP also offers a degree of design freedom which is not found in other materials. It is expected to be used in applications such as gas adsorption, storage, separation, and catalysts.
HKUST-1
| Substance | HKUST-1 |
|---|---|
| Formula | Cu3(C9H3O6)2 |
| CAS No. | 51937-85-0 |
| BET Specific Surface Area | 1,800～1,900 |
| Applications | HKUST-1 is a benchmark compound for micropores. It has excellent gas adsorption properties, including methane adsorption. |
ZIF-8
| Substance | ZIF-8 |
|---|---|
| Formula | Zn(C4H5N2)2 |
| CAS No. | 59061-53-9 |
| BET Specific Surface Area | 1,300～1,500 |
| Applications | ZIF-8 has excellent heat and water resistance, and can be used for propylene/propane separation membranes, etc. |
Uio-66
| Substance | Uio-66 |
|---|---|
| Formula | Zr6(OH)4O4(C8H4O4)6 |
| CAS No. | 1072413-89-8 |
| BET Specific Surface Area | 1,600~1,800 |
| Applications | Uio-66 has excellent chemical and mechanical stability, and is widely used for gas adsorption, catalysts, water purification, etc. |
Nichia can also provide detailed information and consultation on other prototypes.